I've replaced the domain names etc. again, but otherwise its verbatim:
Without adding the users email address as alias under User->SMTP:
Aug 08 16:58:18 example postfix/smtpd[6210]: connect from mout.kundenserver.de[217.72.192.75]
Aug 08 16:58:18 example rspamd[1902]: #1902(rspamd_proxy) <e36d6d>; proxy; proxy_accept_socket: accepted milter connection from ::1 port 46284
Aug 08 16:58:19 example postfix/smtpd[6210]: NOQUEUE: reject: RCPT from mout.kundenserver.de[217.72.192.75]: 550 5.1.1 <test1@example.com>: Recipient address rejected: User unknown in local recipient table; from=<test@company.com> to=<test1@example.com> proto=ESMTP helo=<mout.kundenserver.de>
Aug 08 16:58:19 example rspamd[1902]: #1902(rspamd_proxy) <e36d6d>; milter; rspamd_milter_process_command: got connection from 217.72.192.75:36433
Aug 08 16:58:19 example rspamd[1902]: #1902(rspamd_proxy) <e36d6d>; proxy; proxy_milter_finish_handler: finished milter connection
Aug 08 16:58:19 example postfix/smtpd[6210]: disconnect from mout.kundenserver.de[217.72.192.75] ehlo=2 starttls=1 mail=1 rcpt=0/1 data=0/1 quit=1 commands=5/7
After adding the address as alias:
Aug 08 16:51:10 example postfix/smtpd[5465]: connect from mout.kundenserver.de[212.227.126.131]
Aug 08 16:51:10 example rspamd[1902]: #1902(rspamd_proxy) <12564c>; proxy; proxy_accept_socket: accepted milter connection from ::1 port 35558
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example postfix/smtpd[5465]: 223FA231: client=mout.kundenserver.de[212.227.126.131]
Aug 08 16:51:11 example rspamd[1902]: #1902(rspamd_proxy) <12564c>; milter; rspamd_milter_process_command: got connection from 212.227.126.131:42137
Aug 08 16:51:11 example postfix/cleanup[5469]: 223FA231: message-id=<9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_worker_body_handler: accepted connection from ::1 port 40134, task ptr: 0000000002867C80
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_message_parse: loaded message; id: <9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>; queue-id: <223FA231>; size: 2952; checksum: <4b168492a8dca51534787b99570ae44c>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_spf_record_postprocess: increasing ttl from 282 to 300 as it lower than a limit
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_spf_maybe_return: stored SPF record for company.de (0x408122b154c49443) in LRU cache for 300 seconds, 1/2000 elements in the cache
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_redis_connected: skip obtaining bayes tokens for BAYES_SPAM of classifier bayes: not enough learns 0; 200 required
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_redis_connected: skip obtaining bayes tokens for BAYES_HAM of classifier bayes: not enough learns 0; 200 required
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_stat_classifiers_process: skip statistics as SPAM class is missing
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; lua; greylist.lua:331: Score too low - skip greylisting
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; lua; neural.lua:442: skip ham sample to keep spam/ham balance; probability 1; 0 spam and 1 ham vectors stored
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_task_write_log: id: <9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>, qid: <223FA231>, ip: 212.227.126.131, from: <test@company.com>, (default: F (no action): [-0.40/15.00] [R_SPF_ALLOW(-0.20){+ip4:212.227.126.128/25;},MIME_GOOD(-0.10){text/plain;},RWL_MAILSPIKE_GOOD(-0.10){212.227.126.131:from;},ARC_NA(0.00){},ASN(0.00){asn:8560, ipnet:212.227.0.0/16, country:DE;},DMARC_NA(0.00){company.de;},FROM_EQ_ENVFROM(0.00){},FROM_HAS_DN(0.00){},HAS_XOIP(0.00){},MIME_TRACE(0.00){0:+;},PREVIOUSLY_DELIVERED(0.00){test1@example.com;},RCPT_COUNT_ONE(0.00){1;},RCVD_COUNT_FIVE(0.00){6;},RCVD_TLS_LAST(0.00){},RCVD_VIA_SMTP_AUTH(0.00){},R_DKIM_NA(0.00){},TO_DN_EQ_ADDR_ALL(0.00){},TO_MATCH_ENVRCPT_ALL(0.00){}]), len: 2952, time: 153.605ms, dns req: 18, digest: <4b168492a8dca51534787b99570ae44c>, rcpts: <test1@example.com>, mime_rcpts: <test1@example.com>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_protocol_http_reply: regexp statistics: 154 pcre regexps scanned, 1 regexps matched, 172 regexps total, 11 regexps cached, 21.40KiB scanned using pcre, 21.40KiB scanned total
Aug 08 16:51:11 example postfix/qmgr[1955]: 223FA231: from=<test@company.com>, size=3403, nrcpt=2 (queue active)
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example rspamd[1902]: #1902(rspamd_proxy) <bc84b2>; proxy; proxy_milter_finish_handler: finished milter connection
Aug 08 16:51:11 example postfix/smtpd[5465]: disconnect from mout.kundenserver.de[212.227.126.131] ehlo=2 starttls=1 mail=1 rcpt=1 data=1 quit=1 commands=7
Aug 08 16:51:11 example piler-smtp[1388]: connected from 127.0.0.1:43318 on fd=6 (active connections: 1)
Aug 08 16:51:11 example piler-smtp[1388]: received: 81QXPXFO6SOYMPDY, from=test@company.com, size=3366, client=127.0.0.1, fd=6, fsync=6568
Aug 08 16:51:11 example piler-smtp[1388]: disconnected from 127.0.0.1 on fd=6, slot=0, reason=done (0 active connections)
Aug 08 16:51:11 example postfix/smtp[5472]: 223FA231: to=<archive@example.com>, relay=127.0.0.1[127.0.0.1]:2693, delay=0.29, delays=0.25/0.03/0/0.01, dsn=2.0.0, status=sent (250 OK <81QXPXFO6SOYMPDY>)
Aug 08 16:51:11 example postfix/local[5471]: 223FA231: to=<test1@example.com>, relay=local, delay=0.3, delays=0.25/0.02/0/0.03, dsn=5.1.1, status=bounced (unknown user: "test1")
Aug 08 16:51:11 example postfix/cleanup[5469]: 665E0233: message-id=<20230808145111.665E0233@example.com>
Aug 08 16:51:11 example postfix/bounce[5473]: 223FA231: sender non-delivery notification: 665E0233
Aug 08 16:51:11 example postfix/qmgr[1955]: 665E0233: from=<>, size=5185, nrcpt=1 (queue active)
Aug 08 16:51:11 example postfix/qmgr[1955]: 223FA231: removed
Aug 08 16:51:10 example postfix/smtpd[5465]: connect from mout.kundenserver.de[212.227.126.131]
Aug 08 16:51:10 example rspamd[1902]: #1902(rspamd_proxy) <12564c>; proxy; proxy_accept_socket: accepted milter connection from ::1 port 35558
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example postfix/smtpd[5465]: 223FA231: client=mout.kundenserver.de[212.227.126.131]
Aug 08 16:51:11 example rspamd[1902]: #1902(rspamd_proxy) <12564c>; milter; rspamd_milter_process_command: got connection from 212.227.126.131:42137
Aug 08 16:51:11 example postfix/cleanup[5469]: 223FA231: message-id=<9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_worker_body_handler: accepted connection from ::1 port 40134, task ptr: 0000000002867C80
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_message_parse: loaded message; id: <9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>; queue-id: <223FA231>; size: 2952; checksum: <4b168492a8dca51534787b99570ae44c>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_spf_record_postprocess: increasing ttl from 282 to 300 as it lower than a limit
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_spf_maybe_return: stored SPF record for company.de (0x408122b154c49443) in LRU cache for 300 seconds, 1/2000 elements in the cache
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_redis_connected: skip obtaining bayes tokens for BAYES_SPAM of classifier bayes: not enough learns 0; 200 required
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_redis_connected: skip obtaining bayes tokens for BAYES_HAM of classifier bayes: not enough learns 0; 200 required
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_stat_classifiers_process: skip statistics as SPAM class is missing
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; lua; greylist.lua:331: Score too low - skip greylisting
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; lua; neural.lua:442: skip ham sample to keep spam/ham balance; probability 1; 0 spam and 1 ham vectors stored
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_task_write_log: id: <9909CA663850B240AE42EC008D091529D6D453BE@SERVER01.company.local>, qid: <223FA231>, ip: 212.227.126.131, from: <test@company.com>, (default: F (no action): [-0.40/15.00] [R_SPF_ALLOW(-0.20){+ip4:212.227.126.128/25;},MIME_GOOD(-0.10){text/plain;},RWL_MAILSPIKE_GOOD(-0.10){212.227.126.131:from;},ARC_NA(0.00){},ASN(0.00){asn:8560, ipnet:212.227.0.0/16, country:DE;},DMARC_NA(0.00){company.de;},FROM_EQ_ENVFROM(0.00){},FROM_HAS_DN(0.00){},HAS_XOIP(0.00){},MIME_TRACE(0.00){0:+;},PREVIOUSLY_DELIVERED(0.00){test1@example.com;},RCPT_COUNT_ONE(0.00){1;},RCVD_COUNT_FIVE(0.00){6;},RCVD_TLS_LAST(0.00){},RCVD_VIA_SMTP_AUTH(0.00){},R_DKIM_NA(0.00){},TO_DN_EQ_ADDR_ALL(0.00){},TO_MATCH_ENVRCPT_ALL(0.00){}]), len: 2952, time: 153.605ms, dns req: 18, digest: <4b168492a8dca51534787b99570ae44c>, rcpts: <test1@example.com>, mime_rcpts: <test1@example.com>
Aug 08 16:51:11 example rspamd[1905]: #1905(normal) <94369d>; task; rspamd_protocol_http_reply: regexp statistics: 154 pcre regexps scanned, 1 regexps matched, 172 regexps total, 11 regexps cached, 21.40KiB scanned using pcre, 21.40KiB scanned total
Aug 08 16:51:11 example postfix/qmgr[1955]: 223FA231: from=<test@company.com>, size=3403, nrcpt=2 (queue active)
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example postfix/trivial-rewrite[5468]: warning: do not list domain example.com in BOTH mydestination and virtual_mailbox_domains
Aug 08 16:51:11 example rspamd[1902]: #1902(rspamd_proxy) <bc84b2>; proxy; proxy_milter_finish_handler: finished milter connection
Aug 08 16:51:11 example postfix/smtpd[5465]: disconnect from mout.kundenserver.de[212.227.126.131] ehlo=2 starttls=1 mail=1 rcpt=1 data=1 quit=1 commands=7
Aug 08 16:51:11 example piler-smtp[1388]: connected from 127.0.0.1:43318 on fd=6 (active connections: 1)
Aug 08 16:51:11 example piler-smtp[1388]: received: 81QXPXFO6SOYMPDY, from=test@company.com, size=3366, client=127.0.0.1, fd=6, fsync=6568
Aug 08 16:51:11 example piler-smtp[1388]: disconnected from 127.0.0.1 on fd=6, slot=0, reason=done (0 active connections)
Aug 08 16:51:11 example postfix/smtp[5472]: 223FA231: to=<archive@example.com>, relay=127.0.0.1[127.0.0.1]:2693, delay=0.29, delays=0.25/0.03/0/0.01, dsn=2.0.0, status=sent (250 OK <81QXPXFO6SOYMPDY>)
Aug 08 16:51:11 example postfix/local[5471]: 223FA231: to=<test1@example.com>, relay=local, delay=0.3, delays=0.25/0.02/0/0.03, dsn=5.1.1, status=bounced (unknown user: "test1")
Aug 08 16:51:11 example postfix/cleanup[5469]: 665E0233: message-id=<20230808145111.665E0233@example.com>
Aug 08 16:51:11 example postfix/bounce[5473]: 223FA231: sender non-delivery notification: 665E0233
Aug 08 16:51:11 example postfix/qmgr[1955]: 665E0233: from=<>, size=5185, nrcpt=1 (queue active)
Aug 08 16:51:11 example postfix/qmgr[1955]: 223FA231: removed